[Paper]: Bimetallic Ru:Ni/MCM-48 catalysts for the effective hydrogenation of D – glucose into sorbitol

Three different bimetallic Ru:Ni catalysts supported on a mesoporous silica MCM-48 were prepared by consecutive wet impregnations, with a total metal loading of ca. 3 % (w·w-1). Ru:Ni ratios spanned in the range of 0.15 – 1.39 (w·w-1) and were compared with the corresponding monometallic Ni/MCM-48. The catalysts so prepared were characterized by X-Ray Diffraction, […]

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[Paper] The use of modelling to understand the mechanism of hydrogen peroxide direct synthesis from batch, semibatch and continuous reactor points of view

Hydrogen peroxide direct synthesis was experimentally studied in three different reactors, namely the batch, semibatch and trickle bed reactors (TBR), using a new promising catalyst based on Pd/K2621. Excellent results were obtained from the experimental point of view, achieving high H2O2 selectivities, around 90% for a short contact time in the batch reactor, 60% in […]

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